Here is the Top 10 of the best free chat websites :

http://iwebcam.com

http://chatroulette.com

http://planetlivechat.com

http://www.chatforfree.org

http://tinychat.com

http://www.spinchat.com

http://everywherechat.com

http://vpchat.com

http://www.icq.com

http://www.freechatcode.com

..have fun!