Here is the Top 10 of the best free chat websites :
http://iwebcam.com
http://chatroulette.com
http://planetlivechat.com
http://www.chatforfree.org
http://tinychat.com
http://www.spinchat.com
http://everywherechat.com
http://vpchat.com
http://www.icq.com
http://www.freechatcode.com
..have fun!